はい、あなたはケースを行うことができます:
select case when noOfGirls=0 then noOfBoys
else round(noOfBoys/noOfGirls) end as ration
from student;
しかし、おそらくあなたは望むでしょう:
select case when noOfGirls=0 then 1
else round(noOfBoys/noOfGirls) end as ration
from student;